Preparation and characterization of supported and unsupported nickel complexes. by Salma Karim

Cover of: Preparation and characterization of supported and unsupported nickel complexes. | Salma Karim

Published by Brunel University in Uxbridge .

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ContributionsBrunel University. Department of Chemistry.
The Physical Object
Pagination210p. :
Number of Pages210
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Open LibraryOL20757157M

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JOURNAL OF CATALY () The Preparation, Characterization, and Use of Supported Potassium-Group VIII Metal Complexes as Catalysts for CO Hydrogenation G. MCVICKER AND M. VANNICE' Exxon Research and Engineering Company, Corporate Pioneering Research Laboratories, Linden, New Jersey Received ; revised December 3, A major disadvantage of supported Cited by: Preparation and characterization of supported and unsupported nickel complexes.

Author: Karim, Salma. Metal Particle Size in Silica-Supported Copper Catalysts. Influence of the Conditions of Preparation and of Thermal Pretreatments.

The Journal of Physical Chemistry B(5), DOI: /jpq. Molina and, G. Poncelet. α-Alumina-Supported Nickel Catalysts Prepared with Nickel Acetylacetonate. by: Nickel complex [Ni(1-MeIm)6(BF4)2, 1-MeIm = 1-methylimidazole] has been prepared in 1-butylmethylimidazolium tetrafluoroborate ([bmim]BF4) ionic liquid by a simple solution phase method.

The complex was characterized by elemental analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared absorption spectroscopy (IR) and thermal by: 1. The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and PMHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxymethylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (PMHBdMBn) Schiff-base ligands in methanol.

Synthesis, crystal structure and spectroscopic characterization of silver(I), cadmium(II) complexes with the Schiff base derived from pyridinecarboxaldehyde and 4-[(E)phenyldiazenyl]aniline.

Journal of Coordination Chemistry59 (2), Cited by:   Preparation and characterization of some uracil complexes of nickel (ii) and copper (ii) with ammoni. The energy of activation for the epoxidation of cyclohexene and oxidation of phenol with the polymer‐supported Schiff base complexes of iron(III) ions was and kJ/mol, respectively, but it Preparation and characterization of supported and unsupported nickel complexes.

book found to be higher with the supported HPPn Schiff base complexes of cobalt(II) and nickel(II) ions and with the unsupported HPPn Schiff base Cited by: The subject of this work was the synthesis and characterization of Ni(II) and Cu(II) complexes with potassium 3-dithiocarboxyazaaminopentanoate dihydrate, with par - ticular accent on the thermal behaviour of both the ligand and the complexes.

Synthesis, characterization and biological activity of transition metal complexes of a Schiff base derived from benzoin and 3-ethoxy salicylaldehyde with 2-amino benzoic acid have been detailed. The Ni(II) Schiff base complex derived from salicylaldehyde and o-amino benzoic acid has been prepared and characterized [4], [19].Cited by: 8.

Unsupported Bimetallic Particles Introduction. Synthesis of Unsupported Nanoparticles. Stabilization of Unsupported Nanoparticles. Preparation and Characterization of Ru Nanoparticles Stabilized by Hexadecylamine.

Preparation and Characterization of Ru Nanoparticles Stabilized by Grafted Organometallic FragmentsCited by: 1. Synthesis of a Nickel complex was determined by adding ethylenediamine and ethanol.

After obtaining close to g of nickel(II) sulfate hexahydrate, with your partner as instructed in step one, we quantitatively transferred it to a mL beaker with no more than 3mL of water.

Abstract Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors (supported phospho-tungstate catalysts) in H 2 and characterized by X-ray diffraction (XRD), BET, temperature-programmed desorption of ammonia (NH 3-TPD) and X-ray photoelectron spectroscopy (XPS).The reduction-phosphiding processes of the precursors were investigated by Cited by: 2.

The copper, nickel and chloride contents of the complexes under study were determined and the results are summarized in the following Table Table Data for the copper, nickel and chloride.

The free and polymer-anchored metal complexes were synthesized by the reaction of nickel (II) with one molar equivalent of unsupported N N′-bis (2-Hydroxymethoxybenzaldehyde) 4-Methylbenzene.

Ni 2 P/Ni 12 P 5 nanoparticles were obtained by thermal decomposition of nickel organometallic salt at low temperature.

The use of different characterization techniques allowed us to determine that this process produced a mixture of two nickel phosphide phases: Ni 2 P and Ni 12 P nickel phosphides nanoparticles, supported on mesoporous silica, showed activity and high Cited by: 4. square planar nickel(II)-thiosemicarbazone complexes are associated with conducting and magnetic property and such complexes have potential for use as building block in the preparation of novel molecular material with interesting conducting or magnetic property9, Experimental All reagents and reactants were of analytical grade.

SYNTHESIS AND CHARACTERIZATION OF IRON (II) AND NICKEL (II) SCHIFF BASE COMPLEXES * Aliyu, H. and A. Mohammed Department of Chemistry Bayero University, Kano, P.Kano, Nigeria, *Correspondence author: [email protected] ABSTRACT The complexes of iron (II) and nickel (II) with schiff base derived from benzoin and 2-amino.

Synthesis and Structural Studies of Nickel Complex Supported by-ONNO-Tetra Dentate Schiff-Base Ligand: Efficient Catalysts for Oxidation of Phenol Article (PDF Available) August with Reads.

Improving the effectiveness of catalysts is the best way to ensure cleaner, more efficient industrial processes for a wide range of applications.

Catalyst Preparation: Science and Engineering explores the optimization of catalytic materials through traditional and novel methods of catalyst preparation, characterization, and monitoring on laboratory and industrial scales.

paramagnetical. In a quadratic planar nickel complex the orbitals are all with paired electrons so these complexes are diamagnetical. Discussion: The synthesis of this nickel-complexes does work with the used manual[1]. But the recycling method had a failure-quote of File Size: KB. The group of A 2 BX 4 materials, in which A and B are metallic elements and X is a chalcogen (O, S, Se, Te), has attracted much attention because it offers a versatile range of relevant physical and chemical properties [1, 2].The nickel aluminate NiAl 2 O 4 is an inverse spinel, half of its aluminium ions preferentially fill the tetrahedral sites, and the others fill the octahedral sites.

Preparation and Characterization of SBA Supported Cobalt– Molybdenum Sulfide Catalysts for HDS Reaction: An All Sulfide Route to Hydrodesulfurization Catalysts Z.-D. Huang Æ W.

Bensch Æ L. Kienle Æ S. Fuentes Æ G. Alonso Æ C. Ornelas Received: 18 March /Accepted: 3 May /Published online: 28 May Which factors determine the geometry of metal complexes.

Metal ions in solution are surrounded by an array of ions or molecules called ligandsto form coordination of main group metal ions such as Na(I), Hg(II) or Al(III) (and Cu(I)), which have no lone-pair electrons, have the high symmetry shapes that minimise the ligand-ligand repulsions and at the same time, in the covalent.

Catalyst Preparation. The nickel molybdate nanocatalyst was synthetized in two steps. First, a well-ground mixture of nickel nitrate Ni(NO 3) 2 6H 2 O, ammonium molybdate (NH 4) 6 Mo 7 O 24 4H 2 O, and oxalic acid H 2 C 2 O 4 2H 2 O in the molar ratio 1//10 [] was used to obtain an oxalate precursor after heating at ° chemicals were obtained from Sigma-Aldrich and Cited by: 5.

The molecular structures of the isatin Schiff bases of S- methyldithiocarbazate (Hisasme) and S-benzyldithiocarbazate (Hisasbz) have been determined by X-ray diffraction and their complexes of general formula [ML ]n(solvate) [M = Co, Ni, Zn ; L = anionic forms of Hisasme or Hisasbz; solvate = DMF, DMSO; n = 1, 2] and [Sn(L)PhCl]nMeOH (n = 0, 1) have been synthesized and characterized Cited by: A series of new di- tri- and tetranuclear Co(II) and Cu(II) complexes of three new diSchiff base ligands were synthesized by two different methods.

The first method involved the synthesis of the three ligands from condensation reaction of 3,4-dihydroxybenzaldehyde (L′H 2) with ethylenediamine (en), o-phenylenediamine (o-PD), or 4,5-dimethyl-1,2-phenylendiamine (DMPD) in a mole ratio of 2 Cited by: A Schiff base (SB) is derived from salicylaldehyde and 2-aminopyridine.

The transition metal complexes of N i(II), Cu (II), Co and Cd (II) metal ions were prepared with this Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to Author: Md.

Motahar Hossain, Md. Abul Bashar, Md. Nuruzzaman Khan, Pijush Kanti Roy, Md. Abdul Mannan, Md. The discussion is focused on the synthesis, characterization, and reactivities of complexes featuring both symmetrical and unsymmetrical ligands, ECE and ECE′.

The material is organized into various sections according to the type of donor moiety E and E′ (phosphine, amine, phosphinite, phosphinimine, thioether, and N -heterocyclic carbene.

PUBLICATIONS. BOOK CHAPTERS. 1 Victor N. Nemykin and Eugenii A. Lukyanets, "The key role of the peripheral substituents in the chemistry of phthalocyanines", in: Handbook of Porphyrin Science, K. Kadish, K. Smith and R.

Guilard (Eds.); World Scientific: Singapore,Vol 3., pp 1 - 2 Victor N. Nemykin and Paul Kiprof, "Preparation, UV-Vis and MCD spectroscopy, and molecular. Synthesis and characterization of some new Schiff base ligands derived from various diamines and nitrosalicylaldehyde and their complexes of Ni(II) and Cu(II) are reported.

Several spectral techniques such as UV-Vis, FT-IR, and NMR spectra were used to identify the chemical structures of the reported ligands and their complexes. The ligands are found to be bound to the metal atom through the Cited by: 3. Preparation of Nickel Coordination Complexes Summary: The purpose of this experiment was to synthesize nickel coordination complexes and calculate the percent yield.

In part one, hexaamminenickel II chloride was produced using nickel (II) chloride hexahydrate as a metal ion and ammonium hydroxide as a ligand. The theoretical yield of the reaction was g, the actual yield.

Method 2. In this method the metal complexes were prepared from condensation reaction of the Cu(II) complex precursor (LCuL ′) (L = 2,2′-bipyridyl, L ′ = 4-formylbenzene-1,2-bis(olate)) with the diamines followed by the reaction with the metal salts to form tri- and tetranuclear sis of LCuL ′.

This complex was prepared by following a previously published method Cited by: COMPLEXES OF NICKEL (II) WITH THE SCHIFF BASES DERIVED FROM CONDENSATION OF SALICYLALDEHYDE AND BIS-Ni (AMUH) 2Cl2 T.

Priya Devi*and R. Hemakumar Singh Department of Chemistry, Manipur University, Canchipur, INDIA work have been done on the synthesis and characterization of this compounds with Schiff base ligand.

Read "Essential elucidation for preparation of supported nickel phosphide upon nickel phosphate precursor, Journal of Solid State Chemistry" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.

The Preparation of Nickel(II) Complexes: Linkage Isomers By: Trinidad Reyes. Introduction. The purpose of the nickel (II) complex: linkage isomers experiment was to investigate how the ambidentate properties of the NO 2 ligand behave when it is bonded to a nickel atom with respect to its place in the spectrochemical series.

The NO 2 ligand can be classified as an ambidentate ligand because. In chemistry, a catalyst support is the material, usually a solid with a high surface area, to which a catalyst is affixed.

The activity of heterogeneous catalysts occurs at the surface atoms. Consequently, great effort is made to maximize the surface area of a catalyst. One popular method for increasing surface area involves distributing the catalyst over the support. Vol Issue 2, March ISSN: (Print) X (Online) CO 2 fixation by macrocyclic nickel(II) complexes: synthesis and structures of helical chains constructed via hydrogen bonds involving imidazole.

Preparation, characterization, crystal structures and catalytic oxidation activities of two transition metal. Table The physical properties of amino acid of nickel complexes 34 Table The conductivity of amino acid of nickel complexes 35 Table Molar conductance, A of electrolyte solution which has 35 2,3,4 and 5 ions at 25°C Table Selected infrared data of ligands, salts and complexes Green is the future of chemistry.

Catalysts with high selectivity are the key to green chemistry. Polymer-supported Raney catalysts have been found to have outstanding performance in the clean preparation of some chemicals. For example, a polyamide 6-supported Raney nickel catalyst provided a % conversion of n-butyraldehyde without producing any detectable n-butyl ether, the main Cited by: 3.

Thus, the current study explores the synthesis of four novel water-soluble complexes of the type, [][2] (Figure 2) (where M = [2+], L = 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine-4',4"-disulfonic acid sodium salt/3-(2-pyridyl)-5,6-di(2-furyl)-1,2,4-triazine-5',5"-disulfonic acid disodium salt, and n = 1/2), their chemical characterization, and preliminary tests to assess.Catalysts obtained by the immobilisation of acidic ionic liquids (ILs) on solid supports offer several advantages compared to the use of catalytically active ILs themselves.

Immobilisation may result in an increase in the number of accessible active sites of the catalyst and a reduction of the amount of the IL required. The ionic liquid films on the carrier surfaces provide a homogeneous Cited by: Preparation of supported nickel oxide with tunable particle size via confinement.

Mariska Wolters, Lotte J. W. van Grotel, Jelle R. A. Sietsma, Petra E. de Jongh. and Krijn P. de Jong 1* 1. Inorganic Chemistry and Catalysis, Debye Institute, Utrecht University, CA Utrecht (the Netherlands) *@ Introduction.


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